生物气CO_2还原途径中碳同位素分馏作用研究及应用   总被引：2，自引：0，他引：2  

李谨  胡国艺  张英  杨贵芳  崔会英  曹宏明  胡须龙 《地学前缘》2008,15(5):357

地质历史中,CO2/H2还原产甲烷作用对生物气的形成具有十分重要的意义。中国柴达木盆地第四系生物气主要为CO2/H2还原型生物气。笔者以CO2/H2还原生气理论为指导,进行不同初始碳同位素值和不同赋存状态碳源的生物模拟实验,研究CO2/H2还原产气过程中发生的碳同位素分馏作用。实验结果表明,产物中δ13CH4值与底物的δ13C值呈很好的正相关关系;在反应母质过量的情况下,碳源的赋存状态可以影响产物甲烷的碳同位素组成。以游离形式CO2还原产生的甲烷δ13C值,相对于以HCO3-、CO23-离子形式产生的甲烷δ13C值轻。通过柴达木盆地东部第四系生物气田实例分析,探讨了该区生物气的主要底物CO2的来源及赋存状态,对评价盆地生物气资源和有利勘探区预测有重要的参考价值。  相似文献   

河南板厂银多金属矿床钾长石氩-氩年龄及其地质意义   总被引：4，自引：0，他引：4  

李厚民  王登红  郭保健  陈毓川  白凤军  仇建军 《地球学报》2008,29(2):154-160

河南内乡板厂矿床通过近年来的勘查工作,为一大型斑岩-热液型银铜铅锌(钼)矿床.本文对该矿床斑岩型铜矿石中钾长石进行了Ar-Ar定年,获得两个年龄坪:900～1150℃年龄坪包括了43.4%的39Ar,坪年龄为(148.1±1.6)Ma,反等时线年龄为(145.7±2.3)Ma;1200～1450℃年龄坪包括了48.8%的39Ar,坪年龄为(161.0±1.6)Ma,反等时线年龄(159.0±14.0)Ma.前者代表了该矿床的成矿年龄,后者代表了含矿斑岩的成岩年龄.该二阶段年龄谱特征反映了板厂矿床成岩成矿的阶段性.在我国不少矿区的Ar-Ar法年龄谱上均有多坪显示,这与我国许多矿区成矿作用和构造事件的多期多阶段特征一致.  相似文献   

Laser probe Ar/Ar dating: History and development from a technical perspective     

Hironobu Hyodo   《Gondwana Research》2008,14(4):609

The ⁴⁰Ar/³⁹Ar method using a laser probe opened the door to microscale measurements and diffusion profiles frozen in samples. In the first decade since the initial application of a laser for ⁴⁰Ar/³⁹Ar dating in 1973, practical applications have been few. This is due not only to the fact that the laser and vacuum technologies were immature but that mass spectrometry was also in its infancy. In those days, the sensitivity of a mass spectrometer was generally insufficient to measure the small amount of argon degassed from a geological sample by a laser. These problems have subsequently been solved by new technologies. To understand their current status, a brief history of their development is outlined. This outline focuses on the required detection limit in micro scale measurement, practical approaches for accurate measurement are explained through examples in our laboratory specifically relating to the technical aspects of ⁴⁰Ar/³⁹Ar dating.  相似文献   

Determination of Sr/Sr mass-dependent isotopic fractionation and radiogenic isotope variation of Sr/Sr in the Neoproterozoic Doushantuo Formation     

Takeshi Ohno  Tsuyoshi Komiya  Yuichiro Ueno  Takafumi Hirata  Shigenori Maruyama 《Gondwana Research》2008,14(1-2):126

We measured both mass-dependent isotope fractionation of δ⁸⁸Sr (⁸⁸Sr/⁸⁶Sr) and radiogenic isotopic variation of Sr (⁸⁷Sr/⁸⁶Sr) for the Neoproterozoic Doushantuo Formation that deposited as a cap carbonate immediately above the Marinoan-related Nantuo Tillite. The δ⁸⁸Sr and ⁸⁷Sr/⁸⁶Sr compositions showed three remarkable characteristics: (1) high radiogenic ⁸⁷Sr/⁸⁶Sr values and gradual decrease in the ⁸⁷Sr/⁸⁶Sr ratios, (2) anomalously low δ⁸⁸Sr values at the lower part cap carbonate, and (3) a clear correlation between ⁸⁷Sr/⁸⁶Sr and δ⁸⁸Sr values. These isotopic signatures can be explained by assuming an extreme greenhouse condition after the Marinoan glaciation. Surface seawater, mixed with a large amount of freshwater from continental crusts with high ⁸⁷Sr/⁸⁶Sr and lighter δ⁸⁸Sr ratios, was formed during the extreme global warming after the glacial event. High atmospheric CO₂ content caused sudden precipitation of cap carbonate from the surface seawater with high ⁸⁷Sr/⁸⁶Sr and lighter δ⁸⁸Sr ratios. Subsequently, the mixing of the underlying seawater, with unradiogenic Sr isotope compositions and normal δ⁸⁸Sr ratios, probably caused gradual decrease of the ⁸⁷Sr/⁸⁶Sr ratios of the seawater and deposition of carbonate with normal δ⁸⁸Sr ratios. The combination of ⁸⁷Sr/⁸⁶Sr and δ⁸⁸Sr isotope systematics gives us new insights on the surface evolution after the Snowball Earth.  相似文献   

Environmental tracers as indicators of karst conduits in groundwater in South Dakota,USA   总被引：3，自引：1，他引：2  

Andrew J. Long  J. Foster Sawyer  Larry D. Putnam 《Hydrogeology Journal》2008,16(2):263-280

Environmental tracers sampled from the carbonate Madison aquifer on the eastern flank of the Black Hills, South Dakota, USA indicated the approximate locations of four major karst conduits. Contamination issues are a major concern because these conduits are characterized by direct connections to sinking streams, high groundwater velocities, and proximity to public water supplies. Objectives of the study were to estimate approximate conduit locations and assess possible anthropogenic influences associated with conduits. Anomalies of young groundwater based on chlorofluorocarbons (CFCs), tritium, and electrical conductivity (EC) indicated fast moving, focused flow and thus the likely presence of conduits. δ¹⁸O was useful for determining sources of recharge for each conduit, and nitrate was a useful tracer for assessing flow paths for anthropogenic influences. Two of the four conduits terminate at or near a large spring complex. CFC apparent ages ranged from 15 years near conduits to >50 years in other areas. Nitrate-N concentrations >0.4 mg/L in groundwater were associated with each of the four conduits compared with concentrations ranging from <0.1 to 0.4 mg/L in other areas. These higher nitrate-N concentrations probably do not result from sinking streams but rather from other areas of infiltration.  相似文献   

Water balance in the playa-lakes of an arid environment,Monegros, NE Spain   总被引：1，自引：0，他引：1  

Carmen Castañeda  Miguel Ángel García-Vera 《Hydrogeology Journal》2008,16(1):87-102

The playa-lakes of the Monegros desert in north-east Spain are saline wetlands in an arid environment, a rare phenomenon in Europe. These extremely valuable habitats are threatened by changes associated with agricultural expansion and incorporation of new irrigated areas. An understanding of the present hydrologic regime will enable changes to be identified, particularly those brought about by flooding and pollution caused by irrigation surplus. This study sets out to show the results of applying a daily water balance in three selected playa-lakes. The balance was in two parts and consisted of: (1) the average balance for all the endorheic basin using the BALAN_11 program, and (2) the water balance in some playa-lakes, applying discharge flows obtained from the previous balance. The resulting volumes of water were converted to water depths and contrasted with reference volumes taken from field and Landsat images. The model was calibrated by applying various hypotheses of function which enabled the results to be adjusted. The proposed balance is an acceptable reproduction of field water measurements during this period, and underlines the consistency of the conceptual model. The methodology used is appropriate for understanding the playa-lakes function and for monitoring them for conservation purposes.  相似文献   

Evaluation of distributed recharge in an upland semi-arid karst system: the West Bank Mountain Aquifer,Middle East   总被引：2，自引：0，他引：2  

A. G. Hughes  M. M. Mansour  N. S. Robins 《Hydrogeology Journal》2008,16(5):845-854

Assessment of recharge in a structurally complex upland karst limestone aquifer situated in a semi-arid environment is difficult. Resort to surrogate indicators such as measurement of spring outflow and borehole discharge, is a common alternative, and attempts to apply conventional soil moisture deficit analysis may not adequately account for the intermittent spate conditions that arise in such environments. A modelling approach has been made using the West Bank Mountain Aquifer system in the Middle East as a trial. The model uses object oriented software which allows various objects to be switched on and off. Each of the main recharge processes identified in the West Bank is incorporated. The model allows either conventional soil moisture deficit analysis calculations or wetting threshold calculations to be made as appropriate, and accommodates both direct recharge and secondary recharge. Daily time steps enable recharge and runoff routing to be calculated for each node. Model runs have enabled a series of simulations for each of the three aquifer basins in the West Bank and for the whole of the West Bank. These provide recharge estimates comparable to those prepared by earlier workers by conventional means. The model is adaptable and has been successfully used in other environments.  相似文献   

Groundwater resources in the Jabal Al Hass region,northwest Syria: an assessment of past use and future potential   总被引：2，自引：1，他引：1  

Elco Luijendijk  Adriana Bruggeman 《Hydrogeology Journal》2008,16(3):511-530

In many cases, the development of groundwater resources to boost agricultural production in dry areas has led to a continuous decline in groundwater levels; this has called into question the sustainability of such exploitation. In developing countries, limited budgets and scarce hydrological data often do not allow groundwater resources to be assessed through groundwater modeling. A case study is presented of a low-cost water-balance approach to groundwater resource assessments in a 1,550 km² semi-arid region in northwestern Syria. The past development of irrigated agriculture and its effect on the groundwater system were studied by analysis of Landsat images and long-term groundwater level changes, respectively. All components of the groundwater balance were determined. Groundwater recharge was estimated using the chloride mass balance method. Over the past three decades, groundwater levels have declined, on average, 23 m, coinciding with a two-fold increase in the groundwater-irrigated area. Groundwater resources are currently depleted by a value that lies between 9.5×10⁶ and 118×10⁶ m³ year^?1, which is larger than can be compensated for by a future decrease in natural discharge or changes in boundary conditions. However, groundwater resources are likely to be sufficient to supply domestic and livestock needs in the area.  相似文献   

Lake bank filtration at Nainital,India: water-quality evaluation   总被引：6，自引：2，他引：4  

R. R. Dash  I. Mehrotra  P. Kumar  T. Grischek 《Hydrogeology Journal》2008,16(6):1089-1099

There are different water-supply schemes in Uttarakhand, India to tap the water from streams, rivers and lakes. At Nainital, seven tube-wells (depths 22.6–36.7 m), located at a distance of <100 m from the lake, are being used to abstract (1) lake water after passage through the soil and (2) subsurface water/groundwater flowing towards the lake. Water samples from the lake and tube-wells were analyzed in monsoon and non-monsoon periods from 1997 to 2006. Total dissolved solids, EC, alkalinity and hardness were found to be marginally greater in tube-well waters. The difference in hydrochemistry of tube-well water was mainly due to variation in flow regimes during monsoon and non-monsoon periods. Results clearly indicate that lake water as such is not potable as it contains unacceptable levels of organic matter in terms of COD (~44 mg/L), coliforms (~15.6 × 10⁴ MPN/100 mL) and nutrients. Coliform bacteria and COD have not been detected in any of the tube-well water samples over the years. Lake water, treated by sand filters did not conform to drinking water standards. These investigations have led to the closure of the treatment facility and installation of two tube-wells in addition to the existing five tube-wells.

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Résumé  Il existe divers projets d’alimentation en eau dans l’état d’Uttarakhand, Inde, afin de capter l’eau de ruisseaux, de rivières et de lacs. A Nainital, sept puits tubés (profondeur de 22.6–36.7 m), situés à une distance < à 100 m du lac, sont utilisés pour prélever (1) de l’eau du lac après transit à travers le sol et (2) de l’eau de sub-surface/eau souterraine s’écoulant vers le lac. Des échantillons d’eau du lac et des puits tubés ont été analysés en périodes de mousson et de celles sans mousson 1997 à 2006. Résidu sec, C.E., alcalinité et dureté ont été trouvés marginalement supérieurs dans l’eau des puits tubés. La différence d’hydrochimie de l’eau des puits tubés était surtout due à la variation des régimes d’écoulement pendant les périodes de mousson et de celles sans mousson. Les résultats indiquent clairement que l’eau du lac en tant que telle n’est pas potable car elle contient des teneurs inacceptables de matière organique en termes de COD (~44 mg/L), de coliformes (~15.6 × 10⁴ MPN/100 mL) et d’éléments nutritifs. Des bactéries coliformes et du COD n’ont été détectés dans aucun des échantillons d’eau de puits tubés au fil des années. L’eau du lac traitée par des filtres à sable ne se conformait pas aux normes de l’eau potable. Ces recherches ont conduit à la fermeture de l’installation de traitement et à l’implantation de deux puits tubés en plus des cinq puits existants.

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Resumen  En el estado de Uttarakhand, India, existen diferentes esquemas de abastecimiento de agua que explotan agua de arroyos, ríos y lagos. En Nainital, siete pozos (profundidades entre 22.6–36.7 m), ubicados a una distancia de <100 m del lago, se usan para extraer (1) agua del lago luego de su pasaje a través del suelo y (2) agua superficial y subterránea que fluye hacia el lago. En períodos de monzón y de no monzón de 1997 a 2006 se han analizado muestras de agua del lago y de las captaciones. Se halló que el agua de los pozos es ligeramente mayor en términos del total de sólidos disueltos, la conductividad eléctrica, la alcalinidad y la dureza. La diferencia en la hidroquímica del agua de las perforaciones se debe principalmente a la variación de los regímenes de flujo durante los períodos de monzón y de no monzón. Los resultados claramente indican que el agua del lago no es potable por su contenido inaceptable de materia orgánica medida como demanda de carbono orgánico/oxígeno –DCO- (~44 mg/L), coliformes (~15.6 × 10⁴ NMP/100 mL) y nutrientes. En el período, no se han detectado bacterias coliformes ni DCO en las muestras de agua de las captaciones. El agua del lago, tratada con filtros de arena, no conformó los estándares de agua para bebida. Estas investigaciones han demostrado la necesidad de clausurar las instalaciones de tratamiento y la adición de dos captaciones a las cinco ya existentes.

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New age constraints on emplacement of the Cévenol granitoids, South French Massif Central     

Stéphanie Brichau  Jean-Patrick Respaut  Patrick Monié 《International Journal of Earth Sciences》2008,97(4):725-738

During the development of the Variscan orogeny, large amounts of granitic melt were produced, giving rise to the intrusion of granitoids at different structural levels. Despite numerous studies, ages available from previous work on the Cévennes granites remain largely imprecise. In order to better constrain the age and emplacement mode of these granites, we have combined U–Pb dating on monazites and zircons and ⁴⁰Ar/³⁹Ar dating on biotites with petrological observations, major element chemical analysis and SEM zircon imaging on five samples from the Aigoual–St Guiral–Liron and Mont Lozère granitic massifs. The results revealed that granitic intrusions and cooling in Southern Cévennes occurred in a short time span at ∼306 Ma after the main episode of regional metamorphism. Petrological and chemical data suggest that they result from a mixing between mantle-derived basic magmas (lamprophyres) and lower crust acid magmas. At a regional scale the production of these melts occurred at the end of crustal thickening induced by nappe stacking, at the same time as the late anatectic events recorded further north in the Velay dome and the granulite facies metamorphism recorded in metasedimentary granulite enclaves brought up by Tertiary volcanoes of the Velay area (Bournac).  相似文献